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不同产地丰花玫瑰花水香气成分分析

来源：花匠小妙招时间：2024-12-06 14:31

摘要: 通过对福建省不同产地丰花玫瑰花水香气成分进行比较，探究环境气候条件对丰花玫瑰香气品质的影响，为玫瑰花栽培条件的选择以及提升鲜花品质提供理论依据。采用顶空-气质联用法检测水蒸气蒸馏提取的丰花玫瑰花水中的香气成分，对各成分质谱通过计算机谱库（NIST/WILEY）检索和资料分析，然后结合文献进行人工谱图解析，对福建省不同产地的丰花玫瑰花水主要香气成分进行定性和定量分析。结果表明：从福州市晋安区、屏南县、清流县、泰宁县、漳州市龙文区、柘荣县等产地丰花玫瑰花水中分别鉴定出香气成分48、56、69、44、55、47种，香气成分总相对含量分别为99.88%、99.85%、99.81%、99.82%、99.83%、99.89%。丰花玫瑰花水中主要含萜烯类、酯类、醇类、醛类、酮类、胺类、醚类、芳香族类等成分，其中相对含量较高的香气成分有硼烷二甲硫醚络合物、2-氮杂环丙烷乙基胺、庚醛、芳樟醇、（2S-顺）-四氢化-4-甲基-2-（2-甲基-1-丙烯基）-2H-吡喃、香茅醇、橙花醇、乙酸玫瑰酯、甲基丁香酚等。特征性香气成分香茅醇、橙花醇、玫瑰醚在不同产地丰花玫瑰花水中差异较大，其中福州市晋安区产地玫瑰花水的特征性香气成分相对含量较高，相对含量分别为61.31%、15.48%和1.36%。综上分析表明不同产地对丰花玫瑰花水中的香气成分有一定影响，以福州市晋安区产地丰花玫瑰花水的头香充足，香气层次丰富，香气品质最佳，具有多种抗菌、抗癌、抗炎、抗抑郁生理活性。

关键词: 丰花玫瑰 / 花水 / 香气成分 / 产地

Abstract: Through the comparison of aroma components in the water of Fenghua rose from different producing areas in Fujian Province, the influence of environmental and climatic conditions on the aroma quality of Fenghua rose was explored, thus to provide theoretical basis for the selection of cultivation conditions of rose and the improvement of flower quality. The aroma components in the water of Fenghua rose extracted by steam distillation were detected by using the static headspace-gas chromatography-mass spectrometry method. The mass spectra of each component were searched and analyzed by computer spectral library (NIST/WILEY), and the artificial spectrogram was analyzed by combining with the literatures. Then, the main aroma components in the water of Fenghua rose from different producing areas in Fujian Province were analyzed qualitatively and quantitatively. The results showed that 48, 56, 69, 44, 55, 47 aroma components were respectively identified from the water of Fenghua roses in Jin'an District of Fuzhou, Pingnan County, Qingliu County, Taining County, Longwen District of Zhangzhou and Zherong County, and the total relative contents of aroma components were respectively 99.88%, 99.85%, 99.81%, 99.82%, 99.83% and 99.89%. The water of Fenghua rose mainly contained the components such as terpenes, esters, alcohols, aldehydes, ketones, amines, ethers, aromatic species, etc., among which the aroma components with high relative content were borane dimethyl sulfide complex compound, 2-aziridine ethylamine, heptanal, linalool, (2S-cis)-tetrahydro-4-methyl-2-(2-methyl-1-allyl) -2H-pyran, citronellol, nerol, rhodinyl acetate, methyleugenol, etc. The characteristic aroma components such as citronellol, nerol and rose oxide varied greatly in the water of Fenghua rose from different producing areas in Fujian, among which the relative contents of the characteristic aroma components in the water of Fenghua rose from Jin'an District of Fuzhou were higher, being 61.31%, 15.48% and 1.36%, respectively. In conclusion, the analysis showed that different producing areas had certain influence on the aroma components in the water of Fenghua rose. The water of Fenghua rose from Jin'an District of Fuzhou had abundant top fragrance, rich fragrance levels and the best aroma quality, which had a variety of antibacterial, anticancer, anti-inflammatory and anti-depression physiological activities.

[1] 王辉, 姚雷.油用玫瑰国内外发展现状和研究进展[J]. 香料香精化妆品, 2012(2):47-51. [2]

NIKBAKHT A, KAFI M.A study on the relationships between Iranian people and damask rose (Rosa damascena) and its therapeutic and healing properties[J]. Acta Horticulturae, 2008, 790(790):251-254.

[3] 杨柳, 崔亚宁, 刘松, 等.大马士革玫瑰1号精油香气成分的分析[J]. 北京农学院学报, 2015, 30(3):19-23. [4] 郭永来, 张静菊, 郭锋, 等.格拉斯玫瑰花渣精油的成分分析[J]. 香料香精化妆品, 2012(4):17-21. [5] 张静菊, 郭永来, 李凤英, 等.用分子蒸馏技术提取的玫瑰精油的成分分析[J]. 香料香精化妆品, 2011(4):17-20. [6] 虞伊林, 王秋云, 姚雷.玫瑰自然香气成分及含量变化分析[J]. 上海交通大学学报(农业科学版), 2012, 30(2):80-87. [7]

REN J W, YANG L N, WANG Y, et al.Chemical profile of floral scent at different flower developmental stages of rose de rescht (Rosa damascena Mill.) cultivated in Beijing[J]. Taylor & Francis, 2016, 19(2):433-443.

[8] 姚晨阳, 葛红, 吴华, 等.玫瑰不同品种花瓣挥发性成分分析[J]. 园艺学报, 2019, 46(2):375-384. [9] 员梦梦, 李保印, 周秀梅.静态顶空进样-气质联用法测定玫瑰花香成分[J]. 食品工业科技, 2016, 37(20):101-103. [10] 冯立国, 生利霞, 陶俊, 等.不同种源野生玫瑰鲜花芳香成分的比较研究[J]. 扬州大学学报(农业与生命科学版), 2009, 30(4):90-94. [11] 李源栋, 刘秀明, 邱杰斐, 等.不同产地大马士革玫瑰精油成分比较与分析[J]. 中国食品添加剂, 2019, 30(7):64-72. [12] 冯立国, 生利霞, 赵兰勇, 等.玫瑰花发育过程中芳香成分及含量的变化[J]. 中国农业科学, 2008, 41(12):4341-4351. [13] 李爱萍, 徐晓俞, 陈峥, 等.不同加工工艺与收集时段对‘大马士革’玫瑰花水香气成分的影响[J]. 中国农业科学, 2017, 50(4):720-731. [14] 李国明, 张丽萍, 胡永亮, 等.GC-MS法分析瑞丽柠檬香茅草精油化学成分[J]. 热带农业科学, 2018, 38(2):87-92. [15] 冯庆华.玫瑰精油系列产品的提取及工艺研究[D]. 兰州:兰州大学, 2010. [16] 向晓龙, 杨文, 刘惠芳, 等.香茅醇不同旋光异构体对抑制茶炭疽病病菌活性的比较及其协同作用[J]. 茶叶科学, 2019, 39(4):425-430. [17] 李晓晴, 惠海英, 骆志成.香叶醇、β-香茅醇和丁香酚抗念珠菌活性的体外研究[J]. 现代检验医学杂志, 2016, 31(2):87-89. [18] 童周.浙江玫瑰精油成分、抑菌抗氧化能力及稳定性研究[D]. 杭州:浙江工商大学, 2017. [19]

SHINTARO S, JUN-ICHI O, RYU I, et al.Preventive effect of geraniol on diethylnitrosamine-induced hepatocarcinogenesis in rats[J]. Yonago Acta Medica, 2016, 59(1):37-43.

[20]

JUN T, ZENG X B, ZENG H, et al.Investigations on the antifungal effect of nerol against Aspergillus flavus causing food spoilage[J]. The Scientific World Journal, 2013(2013):1-8.

[21] 赵彩云, 薛洁, 蔡旭东, 等.玫瑰深加工产品关键香气成分的分析[J]. 食品与发酵工业, 2013, 39(12):157-161. [22] 罗婧.玫瑰精油特征香气组成与香韵结构的相互协同作用机制研究[D]. 上海:上海应用技术大学, 2018. [23] 易清元, 江明, 杨艳琼, 等.香叶天竺葵多倍体精油的化学成分研究[J]. 中国农学通报, 2014, 30(3):244-249. [24]

NONATO F R, SANTANA D G, DE MELO F M, et al.Anti-inflammatory properties of rose oxide[J]. International Immunopharmacology, 2012, 14(4):779-784.

[25]

WCLEUBIANNE M N M, DE ANDRADE FRANCISCO D C P, LIVIA A F, et al.Antidepressant activity of rose oxide essential oil:possible involvement of serotonergic transmission[J]. Heliyon, 2021, 7(4):e06620.

[26] 尹爱国, 曾霞, 纪秀玲, 等.复合龙眼果醋的醋酸发酵工艺优化及其风味成分分析[J]. 食品研究与开发, 2018, 39(23):102-107. [27] 左右.JECFA标准介绍(八)[J]. 香料香精化妆品, 2009(2):48-49. [28] 魏长庆.新疆胡麻油特征香气成分鉴别及其产生机制研究[D]. 无锡:江南大学, 2015. [29] 王梦琪, 朱荫, 张悦, 等."清香"绿茶的挥发性成分及其关键香气成分分析[J]. 食品科学, 2019, 40(22):219-228. [30] 孙和龙.α-水芹烯及壬醛对番茄圆弧青霉和灰霉的抑菌作用研究[D]. 湘潭:湘潭大学, 2017. [31] 孙宁泽.改善活性肽口感新型制剂研究[D]. 武汉:华中科技大学, 2017. [32] 周凡, 李春萍, 何欣, 等.温室与外塘养殖下中华鳖日本品系肌肉中挥发性成分的测定[J]. 食品科技, 2014, 39(1):293-298. [33] 陈丛瑾, 杨国恩, 袁列江, 等.HS-SPME/GC-MS法分析香椿芽、叶的挥发性化学成分[J]. 精细化工, 2009, 26(11):1080-1084.