首页分享 Zirconium Tungstate (ZrW2O8)/Polyimide Nanocomposites Exhibiting Reduced Coefficient of Thermal Expansion

Zirconium Tungstate (ZrW2O8)/Polyimide Nanocomposites Exhibiting Reduced Coefficient of Thermal Expansion

来源：花匠小妙招时间：2025-07-28 15:29

ArticleMarch 16, 2005

Zirconium Tungstate (ZrW2O8)/Polyimide Nanocomposites Exhibiting Reduced Coefficient of Thermal Expansion
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Lisa M. SullivanCharles M. Lukehart

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Chemistry of Materials

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Published March 16, 2005

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Abstract

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ZrW2O8 is obtained as microparticulate powder following traditional methods or as nanoparticulate powder using an inverse micelle sol−gel synthesis strategy. As-prepared ZrW2O8 powders, surface-derivatized with (3-aminopropyl)siloxy linker molecules, disperse well in BTDA-ODA polyamic acid resins to give thermally cured ZrW2O8/polyimide hybrid films showing good wetting of embedded ceramic particles. Measured CTE values of ZrW2O8/BTDA-ODA hybrid films containing 0−50 wt % (0−22 vol %) ceramic loading show a controlled reduction in thermal expansion with increasing ceramic content. Reduction in CTE is modeled best assuming mixed-law behavior with incorporation of an interfacial phase region. A 22 vol % ceramic loading gives a 30% (10 ppm/K) reduction of CTE. ZrW2O8/BTDA-ODA films containing 0.8 vol % (3 wt %) ceramic loading exhibit unusually low thermal expansion, although the significance of this observation remains to be confirmed.

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